5/6/2023 0 Comments Domino meaningSynthesis and the potential of thiaheterohelicenes: 06OBC2518. Structure of fullerenes and fullereno-annulated heterocycles problem of fullerene chirality: 06CRV5049. Principles and recent applications of chiral auxiliaries: 06S1899. One-pot synthesis of fused aromatics, particularly, those with diazapentaphene skeleton possessing helical chirality and assignment of absolute configuration assisted by theoretical circular dichroism: 05Y798. Lewis acid–base bifunctional asymmetric catalysis, particularly, in the Reissert reaction: 05SL1491. In this review the authors have described several domino processes to show that stereoselectivity and efficiency can very well be combined and they hope that this reaction concept will in the future be used even more often to access complex carbo- and heterocyclic structures of drugs, natural products, and materials.Īsymmetric domino reactions based on the use of chiral auxiliaries: 06T1619.Īsymmetric domino reactions based on the use of chiral catalysts and biocatalysts: 06T2143.Īsymmetric organocatalysis (general monograph): 05MI13.Īsymmetric organocatalysis of Diels–Alder, and cycloaddition reactions: 05Y464.Īsymmetric catalysis by chiral hydrogen-bond donors, particularly, by proline and alkaloids: 06AG(E)1520.Īsymmetric heterogeneous catalysis (heterocycles as catalysts, starting compounds and products): 06AG(E)4732.Ĭatalytic enantioselective construction of all-carbon quaternary stereocenters: 06S369.Ĭrystallization-induced diastereomer transformations: 06CRV2711.ĭynamic stereochemical rearrangements in chiral organometallic complexes with heterocyclic ligands: 07CSR551.Įfficiency in nonenzymatic kinetic resolution of chiral heterocycles: 05AG(E)3974.Įnantioselective organocatalysis (general monograph): 07MI3.Įxciting supramolecular architectures: Light-induced processes and synthetic transformations in noncovalent assemblies: 05EJO4041. Since the synthetic effort toward natural products and other interesting compounds requires the introduction of usually several stereogenic centers or other stereogenic elements such as axial and helical chirality, the diastereoselectivity of a given reaction is of high importance. 84 The development of sequences that combine transformations of differing fundamental mechanisms broadens the scope of their application in synthetic chemistry. Schild, in Comprehensive Chirality, 2012 2.5.6 Conclusionĭomino reactions have received great attention in recent years as an efficient synthetic methodology for the construction of structurally complex molecules starting from simple materials, because they have several inherent advantages over multistep syntheses: bond forming as well as time and cost efficiency, atom economy, environmental friendliness as well as applicability to diversity-oriented high-throughput synthesis and combinatorial chemistry in the form of multicomponent transformations. The company had originally planned to add a new dot every time it opened a new outlet, but that intention was never realized.L.F. The three dots stand for the first three Domino’s restaurants. The squares on the logo make on think of a pizza box. Also, the new name gave Monaghan an excellent idea on the future logo. That option turned out to be an ideal fit for several reasons.įirst of all, “Domino’s” sounded very much like “DomiNick”, which made the restaurant recognizable among the regulars. One of the delivery boys suggested the name “Domino’s”. Not being allowed to use the existing name, Monaghan had to come up with a new one. What does domino has to do with pizza? To crack that riddle, let’s go back to the 60s when a businessman named Tom Monaghan purchased the DomiNick’s pizza restaurant.
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